胡兴邦
职务: 化工学科主任
联系电话:
办公地址: D406
电子邮箱: huxb@nju.edu.cn
课题组主页:
个人简介

胡兴邦,教授、博导。2002年在浙江大学获理学学士学位,2007年在浙江大学获工学博士学位(导师:李浩然教授),2009年起在威尼斯wnsr888(亚洲)集团有限公司工作,2013-2015年在加州大学圣地亚哥分校Guy Bertrand课题组访学。目前担任中国化工学会离子液体专业委员会青年委员。

研究方向:绿色化工、气体小分子的分离与转化(包括CO2、SO2、H2S、CO、O2等)。就以上研究内容,以第一或通讯作者身份在Nature Catal., AIChE J.,J. Am. Chem. Soc., Angew. Chem. Int. Ed., Chem. Eng. J., J. Catal., Green Chem.等刊物上发表论文70多篇,申请专利22项(授权12项)。曾获全国百篇优秀博士论文提名奖,2010年国家技术发明二等奖(5/6),2009年教育部科技进步二等奖 (6/10),2008年中国石油与化工协会科技进步一等奖(6/10), 2017年中国石油与化工协会技术发明一等奖(6/10)。

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工作经历

20191-至今,南京大学,威尼斯wnsr888,教授、博导

20133-20153月,加州大学圣地亚哥分校,访问学者

20099-2018年12月,南京大学,威尼斯wnsr888,副教授

20077-20098月,浙江大学,化学系,博士后

20029-20077月,浙江大学,化工系,博士生

19989-20027月,浙江大学,化学系,本科生


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研究方向

1.绿色化工&清洁生产

2.高效催化

3.气体小分子的分离与转化(包括CO2、SO2、H2S、CO、O2等)

学术成果

获奖:

1.       胡兴邦,绿色空气氧化催化剂的设计、合成及应用,全国百篇优秀博士论文提名奖2009

2.       李浩然; 陈志荣; 胡柏剡; 王从敏; 胡兴邦; 黄国东, 脂溶性维生素及类胡萝卜素的绿色合成新工艺及产业化, 国家技术发明二等奖2010

3.       李浩然; 陈志荣; 胡柏剡; 王从敏; 王正江; 胡兴邦; 王拥军; 毛建拥; 陈晓阳; 张志香, 维生素E绿色生产工艺的开发及产业化,教育部科技进步二等奖, 2009

4.       张志炳, 周政, 张 锋, 李磊, 孟为民, 胡兴邦, 陈懿, 朱益民, 杨毅融, 杨占平, 微界面传质强化反应-精细分离成套技术研发, 中国石油和化学工业联合会技术发明一等奖, 2017

5.       李浩然; 陈志荣; 胡兴邦; 王从敏; 胡柏剡, 氧代异佛尔酮的制备方法, 中国专利优秀奖, 2011

6.       李浩然; 陈志荣; 胡柏剡; 王从敏; 王正江; 胡兴邦; 王拥军; 毛建拥; 陈晓阳; 张志香, 维生素E绿色生产工艺的开发及产业化, 中国石油和化学工业联合会科技进步一等奖, 2008


第一或通讯作者论文:

1.Romero, E. A.; Zhao, T. X.; Nakano, R.; Hu, X. B.*; Wu, Y. T.; Jazzar, R.*; Bertrand, G.* “Tandem Copper Hydride-Lewis Pair Catalyzed Reduction of Carbon Dioxide into Formatewith Dihydrogen”, Nature Catal.2018, 1, 743-747.

2.Zhao, T. X.; Hu, X. B.*; Wu, Y. T.*; Zhang, Z. B. “Hydrogenation of CO2 to Formate with H2: Transition Metal Free Catalyst Based on a Lewis Pair”, Angew. Chem. Int. Ed.2019, 58, 722-726.

3.Hu, X. B.*; Soleihavoup, M.; Melaimi, M.; Chu, J. X.; Bertrand, G.* “Air-Stable (CAAC) CuCl and (CAAC)CuBH4 Complexes as Catalysts for the Hydrolytic Dehydrogenation of BH3NH3”, Angew. Chem. Int. Ed.2015, 54, 6008-6011.

4.Hu, X. B.; Martin, D.; Melaimi, M.; Bertrand, G.* “Gold-catalyzed hydroarylation of alkenes with dialkylanilines”, J. Am. Chem. Soc. 2014, 136, 13594-13597.

5.Zheng, W. T.; Huang, K.; Wu, Y. T.*; Hu, X. B.* “Protic Ionic Liquid as Excellent Shuttle of MDEA for Fast Capture of CO2”, AIChE J.2018, 64, 209-219.

6.Huang, K.; Zhang, X. M.; Xu, Y.; Wu, Y. T.*; Hu, X. B.*“Protic ionic liquids for the selective absorption of H2S from CO2: Thermodynamic Analysis”,AIChE J.2014, 60, 4232-4240.

7.Huang, K.; Cai, D.; Chen, Y. L.; Wu, Y. T.*; Hu, X. B.*; Zhang, Z. B. “Thermodynamic validation of 1-Alkyl-3-methylimidazolium carboxylates as task-specific ionic liquids for H2S absorption”,AIChE J.2013, 59, 2227-2235.

8.Huang, K.; Wu, Y. T.*; Hu, X. B.* “Effect of alkalinity on absorption capacity and selectivity of SO2 and H2S over CO2: Substituted benzoate-based ionic liquids as the study platform”, Chem. Eng. J. 2016, 297, 265-276.

9.Zhang, X. M.; Huang, K.; Xia, S.; Chen, Y. L.; Wu, Y. T.*; Hu, X. B.*, “Low-viscous fluorine-substituted phenolic ionic liquids with high performance for capture of CO2, Chem. Eng. J. 2015, 274, 30-38.

10.Huang, K.; Chen, Y. L.; Zhang, X. M.; Xia, S.; Wu, Y. T.*; Hu, X. B.* “SO2 absorption in acid salt ionic liquids/sulfolane binary mixtures: Experimental study and thermodynamic analysis”,Chem. Eng. J. 2014, 237, 478-486.

11.Huang, K.; Lu, J.; Wu, Y. T.*; Hu, X. B.*; Zhang, Z. B. “Absorption of SO2 in aqueous solutions of mixed hydroxylammonium dicarboxylate ionic liquids”,Chem. Eng. J. 2013, 215, 36-44.

12.Liu, J.; Yang, G. Q.; Liu, Y.; Wu, D. S.; Hu, X. B.*; Zhang, Z. B.* “Metal-free imidazolium hydrogen carbonate ionic liquids as bifunctional catalyst for the one-pot synthesis of cyclic carbonates from olefins and CO2”,GreenChem. 201921, 3834 - 3838.

13.Yang, G. Q.; Du, H. Y.; Liu, J.; Zhou, Z.; Hu, X. B.*; Zhang, Z. B.* “Oxidation of olefins using molecular oxygen catalyzed by a part per million level of recyclable copper catalyst under mild conditions”, GreenChem., 2017, 19, 675-681.

14.Huang, K.; Feng, X.; Zhang, X.; Wu, Y. T.*; Hu, X. B.*“The ionic liquid-mediated Claus reaction: a highly efficient capture and conversion of hydrogen sulfide”, GreenChem., 2016, 18, 1859-1863.

15.Xu, Y.; Hu, X. B.*; Shao, J.; Yang, G. Q.; Wu, Y. T.*; Zhang, Z. B. “Hydration of alkynes at room temperature catalyzed by gold(I) isocyanide compounds”, GreenChem., 2015, 17, 532-537.

16.Hu, X. B.; Li, Y. X.; Huang, K.; Ma, S.; Yu, H.; Wu, Y. T.*; Zhang, Z. B. “Impact of α-D-glucose pentaacetate on the selective separation of CO2 and SO2 in supported ionic liquid membranes”, Green Chem.2012, 14, 1440-1446.

17.Tu, Z. H.; Zhang, Y. Y.; Wu, Y. T.*; Hu, X. B.* “Self-enhancement of CO reversible absorption accompanied by phase transition in protic chlorocuprate ionic liquids for effective CO separation from N2”,Chem. Commun. 201955, 3390-3393.

18.Yang, L.; Hu, X. B.*; Wu, Y. T.* “The Influence of Axial Ligands on the Catalytic Activity and Enantioselectivity of Salen-Mn Complexes in the Asymmetric Epoxidation”,J. Phys. Org. Chem. 201932e3972.

19.Zhang, X. M.; Xiong, W. J.; Tu, Z. H.; Peng, L. L.; Wu, Y. T.*; Hu, X. B.* “Supported ionic liquid membranes with dual-site interaction mechanism for efficient separation of CO2”, ACS Sustainable Chem. Eng. 20197, 10792-10799.

20.Zhao, T. X.; Liang, J.; Zhang, Y. T.; Wu, Y. T.*; Hu, X. B.*Unexpectedly efficient SO2 capture and conversion to sulfur in novel imidazole-based deep eutectic solvents, Chem. Commun. 201854, 8964-8967.

21.Zhao, T. X.; Li, Y. F.; Zhang, Y. T.; Wu, Y. T.*; Hu, X. B.* Efficient SO2 Capture and Fixation to Cyclic Sulfites by Dual Ether-Functionalized Protic Ionic Liquids without Any Additives, ACS Sustainable Chem. Eng. 20186, 10886-10895.

22.Zhao, T. X.; Zhang, Y. Y.; Liang, J.; Li, P.; Hu, X. B.*; Wu, Y. T.* Multisite activation of epoxides by recyclable CaI2/N-methyldiethanolamine catalyst for CO2 fixation: A facile access to cyclic carbonates under mild conditions, Mole. Catal. 2018, 450, 87-94.

23.Zheng, W. T.; Wu, D. S.; Feng, X.; Hu, J. L.; Zhang, F.; Wu, Y. T.*; Hu, X. B.* Low viscous Protic ionic liquids functionalized with multiple Lewis Base for highly efficient capture of H2S, J. Mole. Liq.2018, 263, 209-217.

24.Zhao, T. X.; Li, P.; Feng, X.; Hu, X. B.*; Wu, Y. T.* Study on absorption and spectral properties of H2S in carboxylate protic ionic liquids with low viscosity, J. Mole. Liq.2018, 266, 806-813.

25.Zhao, T. X.; Zhang, X. M.; Tu, Z. H.; Wu, Y. T.*; Hu, X. B.*Low-viscous diamino protic ionic liquids with fluorine-substituted phenolic anions for improving CO2 reversible capture, J. Mole. Liq.2018, 268, 617-624.

26.Wu, H. Z.; Zhao, T. X.; Hu, X. B.* Friedel-Crafts Reaction of N,N-Dimethylaniline with Alkenes Catalyzed by Cyclic Diaminocarbene-Gold(I) Complex, Sci. Rep.2018, 8, 11449.

27.Zhao, T. X.; Zhai, G. W.; Liang, J.; Li, P.; Hu, X. B.*; Wu, Y. T.* “Catalyst-free N-formylation of amines using BH3NH3 and CO2 under mild conditions”, Chem. Commun.2017, 53, 8046-8049.

28.Zhao, T. X.; Hu, X. B.*; Wu, D. S.; Li, R.; Yang, G. Q.; Wu, Y. T.* “Direct synthesis of dimethyl carbonate from CO2 and methanol at room temperature using imidazolium hydrogen carbonate ionic liquid as recyclable catalyst and dehydrant”, ChemSusChem, 2017, 10, 2046-2052.

29.Zhang, X. M.; Tu, Z. H.; Li, H.; Huang, K.; Hu, X. B.*; Wu, Y. T. *; MacFarlane, D. R.* “Selective separation of H2S and CO2 from CH4 by supported ionic liquid membranes”, J. Membrane Sci.2017, 543, 282-287.

30.Zheng, W. T.; Zhang, F.; Wu, Y. T.*; Hu, X. B.* “Concentrated aqueous solutions of protic ionic liquids as effective CO2 absorbents with high absorption capacities”, J. Mole. Liq.2017, 243, 169-177.

31.Zhang, X. M.; Tu, Z. H.; Li, H.; Li, L.; Wu, Y. T.*; Hu, X. B. “Supported protic-ionic-liquid membranes with facilitated transport mechanism for the selective separation of CO2”, J. Membrane Sci.2017, 527, 60-67.

32.Huang, K.; Zhang, J.; Hu, X. B.; Wu, Y. T.*, “Absorption of H2S and CO2 in Aqueous Solutions of Tertiary-Amine Functionalized Protic Ionic Liquids”, Energy Fuels, 2017, 31, 14060-14069.

33.Xu, Y.; Hu, X. B.*; Zhang, S. F.; Xi, X. X.; Wu, Y. T. * “Room-Temperature Hydration of Alkynes Catalyzed by Different Carbene Gold Complexes and their Precursors”, ChemCatChem2016, 8, 262-267.

34.Zhang, X. M.; Feng, X.; Li, H.; Peng, J.; Wu, Y. T.*; Hu, X. B.* “Cyano-Containing Protic Ionic Liquids for Highly Selective Absorption of SO2 from CO2: Experimental Study and Theoretical Analysis”, Ind. Eng. Chem. Res.2016, 55, 11012-11021.

35.Huang, K.; Zhang, X. M.; Hu, X. B.; Wu, Y. T.* “Hydrophobic protic ionic liquids tethered with tertiary amine group for highly efficient and selective absorption of H2S from CO2”, AIChE J.2016, 62, 4480-4490.

36.Hu, X. B.; Martin, D.*; Bertrand, G.* “Room temperature hydroamination of alkynes with anilines catalyzed by anti-Bredt di(amino) carbene gold(I) complexes”, New J. Chem.2016, 40, 5993-5996.

37.Xi, X. X.; Shao, J.; Hu, X. B.*; Wu, Y. T.* “Structure and asymmetric epoxidation reactivity of chiral Mn(III) salen catalysts modified by different axial anions”, RSC Adv.2015, 5, 80772-80778.

38.Yuan, L. H.; Xu, Y.; Hu, X. B.*; Yang, G. Q.; Wu, Y. T.* “A water-soluble palladium-salen catalyst modified by pyridinium salt showing higher reactivity and recoverability for Heck coupling reaction”, J. Mol. Catal. A: Chem. 2015, 396, 55-60.

39.Huang, K.; Zhang, X. M.; Li, Y. X.; Wu, Y. T.*; Hu, X. B.* “Facilitated separation of CO2 and SO2 through supported liquid membranes using carboxylate-based ionic liquids”,J. Membrane Sci.2014, 471, 227-236.

40.Shao, J.; Yuan, L. H.; Hu, X. B.*; Wu, Y. T.*; Zhang, Z. B. “The effect of nano confinement on the C–H activation and its corresponding structure-activity relationship”Sci. Rep.2014, 4, 7225.

41.Huang, K.; Chen, Y. L.; Zhang, X. M.; Ma, S. L.; Wu, Y. T.*; Hu, X. B.* “Experimental study and thermodynamical modelling of the solubilities of SO2, H2S and CO2 in N-dodecylimidazole and 1,1 '-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)]bis(imidazole): An evaluation of their potential application in the separation of acidic gases”,Fluid Phase Equilib.2014, 378, 21-33.

42.Huang, K.; Xia, S.; Zhang, X. M.; Chen, Y. L.; Wu, Y. T.*; Hu, X. B.* “Comparative Study of the Solubilities of SO2 in Five Low Volatile Organic Solvents (Sulfolane, Ethylene Glycol, Propylene Carbonate, N-Methylimidazole, and N-Methylpyrrolidone)”,J. Chem. Eng. Data2014, 59, 1202-1212.

43.Huang, K.; Cai, D. N.; Chen, Y. L.; Wu, Y. T.*; Hu, X. B.* “Dual Lewis Base Functionalization of Ionic Liquids for Highly Efficient and Selective Capture of H2S”,ChemPlusChem2014, 79, 241-249.

44.Yang, G. Q.; Lin, Q. X.; Hu, X. B.*; Wu, Y. T.; Zhang, Z. B. “Improvement the Activity and Selectivity of Fenton System in the Oxidation of Alcohols”, Journal of Catalysts, 2014, 823054.

45.Huang, K.; Wang, G. N.; Dai, Y.; Wu, Y. T.*; Hu, X. B.* “Dicarboxylic acid salts as task-specific ionic liquids for reversible absorption of SO2 with a low enthalpy change”, RSC Adv.2013, 3, 16264-16269.

46.刘超英,胡兴邦*,吴有庭,离子液体支载金属催化剂的研究进展现代化工2013, 33, 41-45.

47.Hu, X. B.*; Wu, Y. T.*; Zhang, Z. B. “CO oxidation on metal-free nitrogen-doped carbon nanotubes and the related structure–reactivity relationships”, J. Mater. Chem.2012, 22, 15198-15205.

48.Yang, G. Q.; Hu, X. B.*; Wu, Y. T.; Liu, C. Y.; Zhang, Z. B. “Phenol oxidation catalyzed by a simple water-soluble copper catalyst with an imidazole salt tag”, Catal. Commun. 2012, 26, 132-135.

49.Hu, X. B.*; Liu, C. Y.; Wu, Y. T.; Zhang, Z. B. Structure-reactivity relationships of metalloporphyrin modified by ionic liquid and its analogue, J. Phys. Chem. C 2011, 115, 23913-23921.

50.Hu, X. B.; Li, H. R.*; Wu, T. Approaching and bond breaking energies in the C-H activation and their application in catalyst design, J. Phys. Chem. A2011, 115, 904-910.

51.Hu, X. B.*; Zhou, Z.; Lin, Q. X.; Wu, Y. T.*; Zhang, Z. B. High reactivity of metal-free nitrogen-doped carbon nanotube for the C-H activation, Chem. Phys. Lett.2011, 503, 287-291.

52.Hu, X. B.*; Lin, Q. X.; Gao, J. Y.; Wu, Y. T.*; Zhang, Z. B. “Anion–cation and ion-solvent interaction of some typical ionic liquids in solvents with different dielectric constant”, Chem. Phys. Lett.2011, 516, 35-39.

53.Hu, X. B.*; Liu, C. Y.; Wu, Y. T.*; Zhang, Z. B. “Density functional theory study on nitrogen-doped carbon nanotubes with and without oxygen adsorption: the influence of length and diameter”, New J. Chem.2011, 35, 2601-2606.

54.Hu, X. B.; Sun, Y.; Mao, J. Y.; Li, H. R.* Theoretical study on the structure–reactivity relationships of acetylacetone–Fe catalyst modified by ionic compound in C–H activation reaction, J. Catal.2010, 272, 320-332.

55.Hu, X. B.*; Wu, Y. T.; Li, H. R.*; Zhang, Z. B. Adsorption and activation of O2 on nitrogen-doped carbon nanotubes, J. Phys. Chem. C2010, 114, 9603-9607.

56.Hu, X. B.; Mao, J. Y.; Sun, Y.; Chen, H.; Li, H. R. Acetylacetone-Fe catalyst modified by imidazole ionic compound and its application in aerobic oxidation of beta-isophorone, Catal. Commun.2009, 10, 1908-1912.

57.Hu, X. B.; Li, H. R. “Theoretic Research on the Activation and Oxidation of Hydrocarbons”, Prog. Chem.2009, 21, 577-587.

58.Hu, X. B.; Wang, C. M.; Sun, Y.; Sun, H.; Li, H. R. Two unexpected roles of water: Assisting and preventing functions in the oxidation of methane and methanol catalyzed by porphyrin-Fe and porphyrin-SH-Fe, J. Phys. Chem. B 2008, 112, 10684-10688.

59.Hu, X. B.; Li, H. R.; Zhang, L.; Han, S. J. Tautomerism of uracil and 5-bromouracil in a microcosmic environment with water and metal ions. What roles do metal ions play, J. Phys. Chem. B 2007, 111, 9347-9354.

60.Hu, X. B.; Li, H. R. J. Phys. Chem. A 2007, 111, 8352-8356.

61.Hu, X. B.; Li, H. R.; Wang, C. M. The reactivity of all-metal aromatic complexes: A theoretical investigation on the methane activation reaction, J. Phys. Chem. B 2006, 110, 14046-14049.

62.Hu, X. B.; Li, H. R.; Liang, W. C.; Han, S. J. Explore water's protective and assistant role for uracil: A changing role of water at different temperature, Chem. Phys. Lett. 2006, 417, 320-325.

63.Hu, X. B.; Li, H. R.; Wang, C. M.; Han, S. J. How O2 is activated on all-metal aromatic complex (Al4Ca) surface, Chem. Phys. Lett. 2006, 426, 39-42.

64.Hu, X. B.; Li, H. R.; Liang, W. C.; Han, S. J. Reaction mechanism of uracil bromination by HBrO: A new way to generate the enol-keto form of 5-bromouracil, J. Phys. Chem. A 2006, 110, 11188-11193.

65.Hu, X. B.; Li, H. R.; Liang, W. C.; Han, S. J. Exploring a new kind of aromatic hydrogen bond: Hydrogen bonding to all-metal aromatic species, New J. Chem. 2005, 29, 1295-1301.

66.Hu, X. B.; Li, H. R.; Liang, W. C.; Han, S. J. Systematic study of the tautomerism of uracil induced by proton transfer. Exploration of water stabilization and mutagenicity, J. Phys. Chem. B 2005, 109, 5935-5944.

67.Hu, X. B.; Li, H. R.; Liang, W. C. ; Han, S. J. “Explore the effect induced by water in the proton transfer process of 5-fluorouracil”, Acta Phys-Chem. Sin.2005, 21, 952-956.

68.Hu, X. B.; Li, H. R.; Liang, W. C. ; Han, S. J. “Theoretical study on all-metal aromatic complexes: all-metal aromatic hydrogen bond”, Chem. Phys. Lett. 2005, 402, 539-543.

69.Hu, X. B.; Li, H. R.; Ding, J. Y.; Han, S. J. Mutagenic mechanism of the A-T to G-C transition induced by 5-bromouracil: An ab initio study, Biochemistry 2004, 43, 6361-6369.

70.Hu, X. B.; Li, H. R.; Liang, W. C. ; Han, S. J. “Theoretical study on all-metal aromatic complexes: interaction with small gas molecule”, Chem. Phys. Lett. 2004, 397, 180-184.

71.Hu, X. B.; Li, H. R.; Liang, W. C.; Han, S. J. Theoretical study of the proton transfer of Uracil+nH2O (n=0-4): Water stabilization and mutation phenomena for uracil, J. Phys. Chem. B 2004, 108, 12999-13007.


其他论文:

72.Zhao, T. X.; Feng, X.; Zheng, W. T.; Hu, X. B.; Zhang, J. B.*; Wu, Y. T.*, “Solubility of dilute SO2 in binary system of polyethylene glycol 200 and dimethyl sulfoxide as a function of liquid composition and system's spectroscopic studies”, J. Mol. Liq., 2017, 225, 151-159.

73.Chen, Y. L.; Hu, X. B.; Wu, Y. T.* Binary Bronsted Acidic Ionic Liquids (BBAILs) as the Reactive Extraction Intensified Catalysts for the Esterification of Acetic Acid and n-Butanol, J. Chem. Eng. JPN, 2017, 50, 632-640.

74.Huang, K.; Zhang, J.; Hu, X. B.; Wu, Y. T.*, “Absorption of H2S and CO2 in Aqueous Solutions of Tertiary-Amine Functionalized Protic Ionic Liquids”, Energy Fuels, 2017, 31, 14060-14069.

75.Huang, K.; Zhang, X. M.; Hu, X. B.; Wu, Y. T.* “Hydrophobic protic ionic liquids tethered with tertiary amine group for highly efficient and selective absorption of H2S from CO2”, AIChE J.2016, 62, 4480-4490.

76.Chen, Y. L.; Ding, S. Y.; Zheng, W. T.; Zhang, Y. Y.; Wu, Y. T.*; Hu, X. B. Proton-gradient-transfer acid complexes and their catalytic performance for the synthesis of geranyl acetate, Chinese J. Catal.2016, 37, 2114-2121.

77.Cai, D. N.; Huang, K.; Zhang, X. M.; Hu, X. B.; Wu, Y. T.*, “Amino Acid Modified Macroreticular Anion Exchange Resins for CO2 Adsorption”, J. Chem. Eng. JPN.2015, 48, 268-275.

78.Cai, D. N.; Huang, K.; Chen, Y. L.; Hu, X. B.; Wu, Y. T.* “Systematic Study on the General Preparation of Ionic Liquids with High Purity via Hydroxide Intermediates”, Ind. Eng. Chem. Res.2014, 53, 6871-6880.

79.Wang, G. N.; Dai, Y.; Hu, X. B.; Xiao, F.; Wu, Y. T.; Zhang, Z. B. “Novel ionic liquid analogs formed by triethylbutylammonium carboxylate-water mixtures for CO2 absorption”, J. Mol. Liq.2012, 168, 17-20.

80.Tao, D. J.; Wu, Y. T.; Zhou, Z.; Geng, J.; Hu, X. B.; Zhang, Z. B. “Kinetics for the Esterification Reaction of n-Butanol with Acetic Acid Catalyzed by Noncorrosive Bronsted Acidic Ionic Liquids”, Ind. Eng. Chem. Res. 2011, 50, 1989-1996.

81.Sun, Y.; Hu, X. B.; Li, H. R.; Jalbout, A. F. “Comparison between the two different forms of iron(IV)-oxo porphyrin and the effects of neutral axial ligand on their catalysis: A theoretical study”, Comput. Theor. Chem.2011, 966, 62-69.

82.Yun, X.; Hu, X. B.; Jin, Z. Y.; Hu, J. H.; Yan, C.; Yao, J.; Li, H. R. Copper-salen catalysts modified by ionic compounds for the oxidation of cyclohexene by oxygen, J. Mol. Catal. A Chem.2010, 327, 25-31.

83.Sun, Y.; Zhang, W. S.; Hu, X. B.; Li, H. R. “Correlation Analysis of the Substituent Electronic Effects on the Allylic H-Abstraction in Cyclohexene by Phthalimide-N-oxyl Radicals: a DFT Study”, J. Phys. Chem. B2010, 114, 4862-4869.

84.Yao, Z.; Hu, X. B.; Mao, J. Y.; Li, H. R. An environmentally benign catalytic oxidation of cholesteryl acetate with molecular oxygen by using N-hydroxyphthalimide, Green Chem.2009, 11, 2013-2017.

85.Sun, Y.; Hu, X. B.; Li, H. R.; Jalbout, A. F. Metalloporphyrin-dioxygen interactions and the effects of neutral axial ligands, J. Phys. Chem. C 2009, 113, 14316-14323.

86.Wang, C. M.; Guan, W. H.; Xie, P. H.; Yu, X.; Li, H. R.; Hu, X. B.; Wang, Y. “Effects of ionic liquids on the oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone under atmospheric oxygen”, Catal. Commun.2009, 10, 725-727.

87.Mao, J. Y.; Hu, X. B.; Li, H. R.; Sun, Y.; Wang, C. M. Iron chloride supported on pyridine-modified mesoporous silica: An efficient and reusable catalyst for the allylic oxidation of olefins with molecular oxygen, Green Chem.2008, 10, 827-831.

88.Zhang, L; Hu, X. B.; Li, H. R. “Why 1-NH and 3-NH protons of D-biotin exhibit different activities in aqueous solution”, J. Phys. Chem. B 2008, 112, 8779-8782.

89.Shen, Q. C.; Liang, W. C.; Hu, X. B.; Li, H. R. “Molecular dynamics simulation for formamide aqueous solution”, Acta Phys-Chem. Sin.2008, 24, 1169-1174.

90.Guan, W. H.; Wang, C. M.; Yun, X.; Hu, X. B.; Wang, Y.; Li, H. R. “A mild and efficient oxidation of 2,3,6-trimethylphenol to trimethyl-1,4-benzoquinone in ionic liquids”, Catal. Commun.2008, 9, 1979-1981.

91.Jalbout, A. K.; Zhang, L. Q.; Li, H. R.; Hu, X. B. “Proton transfer between 3 ',5 '-methyl phosphate uridine and water: A theoretical study”, Chem. Phys. Lett. 2007, 446, 25-30.

92.Zhang, L.; Li, H. R.; Wang, Y.; Hu, X. B. “Characterizing the structural properties of N,N-dimethylformamide-Based ionic liquid: Density-functional study”, J. Phys. Chem. B 2007, 111, 11016-11020.

93.Zhang, L. Q.; Li, H. R.; Hu, X. B.; Jalbout, A. F. “Theoretical study of the influence of ribose on the proton transfer phenomenon of nucleic acid bases”, Chem. Phys.2007, 337, 110-118.

94.Mao, J. Y.; Li, N.; Li, H. R.; Hu, X. B. “Novel Schiff base complexes as catalysts in aerobic selective oxidation of beta-isophorone”, J. Mol. Catal. A: Chem.2006, 258, 178-184.

95.Liang, W. C.; Li, H. R.; Hu, X. B.; Han, S. J. “Systematic theoretical investigations on all of the tautomers of guanine: From both dynamics and thermodynamics viewpoint”, Chem. Phys.2006, 328, 92-102.

96.Wu, L. H.; Wang, C. M.; Hu, X. B.; Li, H. R. Han, S. J. “(Vapour plus liquid) equilibria for (2-ethoxypropene plus acetone) and (2-ethoxypropene plus butanone)”, J. Chem. Thermodyn.2006, 38, 889-892.

97.Liang, W. C.; Li, H. R.; Hu, X. B.; Han, S. J. “Density functional studies on formamide's water-influenced proton transfer in solution”, Acta Phys-Chem. Sin.2006, 22, 797-803.

98.Zhang, L.; Li, H. R.; Hu, X. B.; Han, S. J. “Microenvironment control of methyl rotation induced by proton transfer”, J. Phys. Chem. A 2006, 110, 7690-7695.

99.Zhang, L.; Li, H. R.; Hu, X. B.; Han, S. J. “1-NH proton of biotin is not always more active than 3-NH proton”, Chem. Phys. Lett. 2006, 421, 334-337.

100.Liang, W. C.; Li, H. R.; Hu, X. B.; Han, S. J. “Proton transfer of formamide plus nH2O (n=0-3): Protective and assistant effect of the water molecule”, J. Phys. Chem. A 2004, 108, 10219-10224.


专利:

1.      胡兴邦,李旭升,吴有庭,张志炳,一种以离子液体为溶剂连续制备原乙酸三甲酯的工艺,专利号:ZL201410047965,授权公告号:CN103787847B,授权日期:2015.11.18

2.      胡兴邦,李建新,吴有庭,李建彬,一种三氯蔗糖生产废气综合利用的方法专利号:ZL201310046265,授权公告号:CN103113197B,授权日期:2014.11.26

3.      胡兴邦,杨国强,吴有庭,张志炳,一类离子液体2-(1-咪唑基)支载的乙酸盐催化剂及其制法专利号:ZL201210002318,授权公告号:CN102553645B,授权日期:2013.10.09

4.      胡兴邦,李建新,李建彬,吴有庭,徐松波,一种合成三氯蔗糖-6-乙酯的新方法” ,公开号­: CN108203452A,公开日:2018.06.26

5.      胡兴邦,李建新,李建彬,吴有庭,徐松波,一种提高三氯蔗糖-6-乙酯结晶收率的方法” ,公开号­: CN108250255A,公开日:2018.07.06

6.      胡兴邦赵天祥,吴有庭,李锐,一种通过二氧化碳和甲醇直接反应制备碳酸二甲酯的方法,公开号­:CN106946706A,公开日:2017.07.14

7.      胡兴邦,杨国强,邵静,吴有庭,张志炳,采用咪唑碳酸氢盐离子液体催化苯甲醛制备安息香的方法,公开号­: CN103242153A,公开日:2013.08.14

8.      胡兴邦,刘超英,吴有庭,张志炳,一类离子液体支载的手性席夫碱金属催化剂及其制法和用途,公开号­: CN103191779A,公开日:2013.07.10

9.  胡兴邦,林秋星,吴有庭,张志炳,催化氧化苯甲醇制备苯甲醛的方法,公开号­: CN102391084A,公开日:2012.03.28

10.      胡兴邦,杨国强,邵静,吴有庭,张志炳,采用咪唑碳酸氢盐离子液体催化苯甲醛制备安息香的方法申请号:,公开号­: CN103242153A,公开日:2013.08.14




课程名称、上课时间地点

《化工过程设计》,《中级应用化学实验》

教学大纲、考试要求
教学资源(上课讲义、参考资料等)
课题组风采