研究生专题报告暨分子有机化学研究中心系列学术报告之二、三

发布时间:2012-03-02浏览次数:4122

题   目: Metal coordination chemistry of N-confused and N-fused porphyrinoids
报告人: Prof. Hiroyuki Furuta
             Department of Chemistry & Biochemistry, Kyushu University
地   点: 费彝民楼一楼报告厅
时   间: 2012年3月14日(星期三)上午9 : 30
联系人: 沈 珍 教授 zsheng@nju.edu.cn;强琚莉 副教授(025-83597090)

EDUCATION and EXPERIENCE:
Website:  http://www.cstf.kyushu-u.ac.jp/~furutalab /
E-mail: hfuruta@cstf.kyushu-u.ac.jp
      2002�present Professor of Chemistry  Kyushu University
      1997 � 2002  Associate Professo   Kyoto University
      1992 � 1997  Associate Professor   Oita University
      1989 � 1992 Postdoctoral Fellow   University of Texas (Austin)  
      1986 � 1989 Postdoctoral Fellow   Mitsubishi Kasei Institute of Life Sciences (Tokyo)  
      1999 � 2002 PRESTO Researche    JST (Organization and Function) 
      2003 � 2007 PRESTO Researcher    JST (Synthesis and Control)  
PUBLICATIONS About 164 research articles in peer-reviewed journals (of which 31 in Angew. Chem. and J. Am. Chem. Soc.) total of 5,113 citations; h-factor = 39

 

题   目:  Supramolecular Porphyrin-Based Molecular Wires
报告人: Prof. Harry. L. Anderson
             Department of Chemistry, Oxford University
地   点: 费彝民楼一楼报告厅
时   间: 2012年3月14日(星期三)上午10:30
联系人: 王乐勇 教授(lywang@nju.edu.cn); 强琚莉 副教授 (jjl@nju.edu.cn, 83597090)

Abstract:
      Porphyrin-based molecular wires exhibit remarkable properties such as wire-like charge transport, strong two-photon absorption, bright near-infrared luminescence and high affinity for carbon nanotubes. They are amazingly amenable to supramolecular control. The well defined coordination chemistry of the metal centers leads wide possibilities for template-directed synthesis and supramolecular control of function. Furthermore, they are spectroscopically eloquent: Their UV-visible and NMR spectra are extremely sensitive to long-range conformational changes, making them ideal structures for testing ideas of multivalent self-assembly.
      This lecture will present recent advances in the supramolecular chemistry of porphyrin-based molecular wires, such as the cooperative formation of the 12-porphyrin nanoring 2:12 DABCO sandwich complex shown below, which has a diameter of 5 nm and is formed in a highly cooperative “all-or-nothing” self-assembly process.

注:此次两个报告算一场研究生专题报告。


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